Yes, rimes is a Scrabble word!
...and is worth 7 points in Scrabble, and 8 points in Words with Friends
rimes
Verb
1. Be similar in sound, especially with respect to the last syllable
2. Compose rhymes
3. Run around the rim of
4. Furnish with a rim
5. Roll around the rim of
Noun
1. Ice crystals forming a white deposit (especially on objects outside)
2. Correspondence in the sounds of two or more lines (especially final sounds)
What Scrabble words can I make with the letters in rimes?
5 Letter Words
4 Letter Words
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3 Letter Words
2 Letter Words