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Yes, grin is a Scrabble word!
...and is worth 5 points in Scrabble, and 7 points in Words with Friends
1. To draw back the lips and reveal the teeth, in a smile, grimace, or snarl
1. A facial expression characterized by turning up the corners of the mouth; usually shows pleasure or amusement
What Scrabble words can I make with the letters in grin?
4 Letter Words
3 Letter Words
2 Letter Words