Yes, grand is a Scrabble word!
...and is worth 7 points in Scrabble, and 9 points in Words with Friends
grand
Adjective
1. Of behavior that is impressive and ambitious in scale or scope
2. Of or befitting a lord
3. Rich and superior in quality
4. Extraordinarily good or great; used especially as intensifiers
5. Of high moral or intellectual value; elevated in nature or style
6. Large and impressive in physical size or extent
7. The most important and magnificent in adornment
8. Used of a person's appearance or behavior; befitting an eminent person
Noun
1. The cardinal number that is the product of 10 and 100
2. A piano with the strings on a horizontal harp-shaped frame; usually supported by three legs
What Scrabble words can I make with the letters in grand?
4 Letter Words
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2 Letter Words