Yes, archly is a Scrabble word!
...and is worth 14 points in Scrabble, and 14 points in Words with Friends
archly
Adverb
1. In_an_arch_manner; with playful slyness or roguishness
What Scrabble words can I make with the letters in archly?
5 Letter Words
4 Letter Words
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3 Letter Words
2 Letter Words