Yes, main is a Scrabble word!
...and is worth 6 points in Scrabble, and 8 points in Words with Friends
main
Adjective
1. Most important element
2. (of a clause) capable of standing syntactically alone as a complete sentence
3. Of force; of the greatest possible intensity
Noun
1. Any very large body of (salt) water
2. A principal pipe in a system that distributes water or gas or electricity or that collects sewage
What Scrabble words can I make with the letters in main?
4 Letter Words
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3 Letter Words
2 Letter Words