Yes, unique is a Scrabble word!
...and is worth 15 points in Scrabble, and 18 points in Words with Friends
unique
Adjective
1. Radically distinctive and without equal
2. (followed by `to') applying exclusively to a given category or condition or locality
3. The single one of its kind
4. Highly unusual or rare but not the single instance
What Scrabble words can I make with the letters in unique?
4 Letter Words
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2 Letter Words