Yes, bluff is a Scrabble word!
...and is worth 13 points in Scrabble, and 16 points in Words with Friends
bluff
Verb
1. Deceive an opponent by a bold bet on an inferior hand with the result that the opponent withdraws a winning hand
2. Frighten someone by pretending to be stronger than one really is
Adjective
1. Very steep; having a prominent and almost vertical front
2. Bluntly direct and outspoken but good-natured
Noun
1. A high steep bank (usually formed by river erosion)
2. Pretense that your position is stronger than it really is
3. The act of bluffing in poker; deception by a false show of confidence in the strength of your cards
What Scrabble words can I make with the letters in bluff?
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Words that can be created with an extra letter added to bluff:
S:bluffs